A Variational formulation of equilibrium statistical mechanics and the Gibbs phase rule
ENTROPIE
RESEAUX
PHYSIQUE STATISTIQUE
SYSTEMES COMPLEXES
Abstract : It is shown that for an infinite lattice system, thermodynamic equilibrium is the solution of a variational problem involving a mean entropy of states introduced earlier [2]. As an application, a version of the Gibbs phase rule is proved.
RUELLE
P/67/X012
IHES
1967
A4
6 f.
EN
TEXTE
PREPUBLICATION
P_67_X012.pdf
1967