A Variational formulation of equilibrium statistical mechanics and the Gibbs phase rule

https://repo-archives.ihes.fr/FONDS_IHES/I_Prepublications/RUELLE/1965-1976/P_67_X012/P_67_X012.pdf

Ruelle, David

RUELLE

1967

Abstract : It is shown that for an infinite lattice system, thermodynamic equilibrium is the solution of a variational problem involving a mean entropy of states introduced earlier [2]. As an application, a version of the Gibbs phase rule is proved.

ENTROPIE

P/67/X012

©IHES

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RUELLE, “A Variational formulation of equilibrium statistical mechanics and the Gibbs phase rule,” Archives de l'IHES, consulté le 18 juin 2024, https://omeka.ihes.fr/document/P_67_X012.pdf.